public class StudentDataRowComparer : IEqualityComparer
    {
        #region IEqualityComparer Members
        public bool Equals(DataRow x, DataRow y)
        {
            return (x.Field("STUDENTID") == y.Field("STUDENTID"));
        }
        public int GetHashCode(DataRow obj)
        {
            return obj.ToString().GetHashCode();
        }
        #endregion
    }
  
How to call it 
...
        //---Make an Union of both tables
        IEnumerable bothTables = dt1.AsEnumerable().Union(dt2.AsEnumerable()); 
                                DataTable dtUnion = bothTables.CopyToDataTable();
        //---Remove Duplicates
        var distinctStudents = dtUnion.AsEnumerable().Distinct( new StudentDataRowComparer());
                                DataTable dtFinal = distinctStudents.CopyToDataTable();